Supramolecular Organization of Bimetallic Building Blocks: from Structural Divertimentos to Potential Applications
DOI:
https://doi.org/10.13052/jsame2245-4551.121Keywords:
Metal-metal interactions, Supramolecular assemblies, MMX Chains, Molecular wires.Abstract
The phenomena that results on supramolecular aggregations of bimetallic
[Pt2L4] and [AuL2] are reviewed. Supramolecular [AuL2]n (n = 2,3) were
observed in some cases in solution as a result of Au(I)···Au(I) aurophilic
interactions, which also direct the assembly of oligomeric structures in crys-
tal phase. Analogously, Pt(II)···Pt(II) attraction accounts for the assembly of
[Pt2L4]nsupramolecules which can result on 1D semiconductive arrangements
in crystal phase and direct the formation of 1D nanofibres on surfaces. Finally,
oxidation of [Pt2L4] to [Pt2L4I]n produces highly conductive polymers that
can reversibly assemble/disassemble into [Pt2L4] and [Pt2L4I2]. Such out-
standing ability results on an unprecedented processability that enables MMX
polymers for technological applications as molecular wires.
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